Answers...

to commonly asked questions.

Outgoing email settings crossed

Whenever I try to send an email using my account, I get the message that I have copied above. Again, I am more than happy to pay you for helping me with this problem.

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From the screenshot, it looks like the outgoing servers for each email address are incorrect. This means that one email account is trying to use the other email account’s outgoing server to deliver its email. And they don’t always like to cooperate. Think of it like asking Fed Ex to deliver a UPS package. That looks why you’re getting a bounce back. Maybe not really enough for one session’s worth but I’m happy to work on it for you if you have some other items as well.
This image is a theme.plist hack